2023 Issue: What Are FRP and CFRPs?

Introduction

These days, technical jargon such as FRP, CFRP, composites, and weight-efficiency often appear in the media for a range of applications. Such terms may be annexed with “lightweight, strong, and non-corrosive” materials that substitute metals. But what exactly are these materials?

Overview

Fiber reinforced plastic (FRP) refers to plastic polymer materials that is fortified with fibers. Carbon Fiber Reinforced Plastics (CFRP), as the name implies, refers to plastics reinforced with carbon fibers. The initial letter refers to the type of fiber used; C being carbon, G being glass fibers, and A being aramid fibers. Since CFRPs are composed from a combination of reinforcing fibers and resin (plastic), they are referred to as a “composite” or “composite material”. In this section, we will introduce the characteristics and applications of CFRP.

Carbon Fiber Characteristics

We will begin by discussing composite materials.

Composite Materials

A composite material is a material composed of two or more different materials with properties not obtainable with a single material. Reinforced concrete, for example, is a composite material whereby the concrete is reinforced with steel bars to improve tensile stress. With fiber-reinforced plastics (FRP), the plastic is fortified with carbon fibers and other materials to produce added strength and properties not exhibited in pure plastics, allowing us to create structures that are far lighter and stronger. While the term “composite” is a less familiar technical jargon, the technique that has been around for a long time.

Classification

Carbon fibers are broadly classified into two types according to the raw materials used.

PAN-based

PAN(Poly-acrylonitrile)-based carbon fiber is produced from acrylonitrile through a series of processes; PAN fiber synthesis, flame retardant treatment, carbonization, graphitization, surface treatment, and sizing. It is predominantly used in structural parts for automobile and aircrafts.

Pitch-based

Pitch-based carbon fiber is composed from coal, petroleum, and coal tar by-products (pitch) through a process of carbonization, surface treatment, and sizing at high temperatures. It is mainly use for industrial-use robot arms and synthetic satellite components.

Resin Characteristics

Resin used as a matrix has two key characteristics which we will discuss below.

Thermosetting Resin

As the name suggests, thermosetting resins are resins that react and harden (cure) when heat is applied. Resins such as polyester, epoxy, phenol, bismaleimide, cyanate, and polyimide are selected and used according to the heat resistance and properties required for the product.

Thermoplastic Resin

Thermoplastics are resins that soften when heated and solidify when cooled—similar to chocolate. Resin types, such as general engineering plastics (PP/PA/PC/TPU) and super engineering plastics (PEI/PPS/PEEK/PEKK) are selected and applied according to the properties required for the product.

Properties/Physical Characteristics

Now that we have covered the material, let’s delve deeper into the unique properties and physical characteristics of CFRP.

Anisotropic Material

In anisotropic materials, strength values vary according to the fiber orientation. Therefore, material design to determine the optimal fiber orientation, type, and volume, is essential to producing both strength and performance.

Highly Heat-resistant

As carbon fibers are carbonized and formed at temperatures exceeding 1,000°C, the heat-resistant level is defined by resin used as the matrix.

Low Specific Gravity

The 1.5-1.7g/cm³ specific gravity exhibited by CFRP clearly demonstrates its superiority to metals in regard to weight reduction, giving due credit to the attention it is receiving.

Superb Strength and Elasticity

CFRP has a wide tensile strength range of 3,000-7,000 MPa and tensile modulus range of 50-900 GPa, depending on the fiber used. It therefore offers superior flexibility for custom designing according to needs and application. This is one of CFRP’s main characteristics.

Dimensional Stability

Resin assumes a low thermal expansion coefficient. While resin used as a matrix has a thermal expansion coefficient on the positive, carbon fiber has a thermal expansion coefficient on the negative. Thus, the type and orientation of the carbon fibers permits a zero thermal expansion, offering possibilities not achievable with non-composite pure plastics.

Other Characteristics

As listing all the merits will drag on, we’ve created a short list of its other characteristics.

Non-rusting, vibration damping, conductivity, fatigue properties, X-ray transmission properties etc.

Applications

So far, we have discussed the key characteristics of CFRP. Now let’s next look at its applications and case studies.

Aircrafts

The body of the widely used Boeing 787 commercial aircraft is largely constructed with CFRP, accounting for approximately 50% of its total body weight. By significantly reducing the body weight, aircrafts are expected to operate more efficiently on long-haul routes, with better fuel efficiency and higher cruise speeds than conventional aircrafts. The enhanced and drastic flexing of the main wings is visible from onboard the plane during take-off. Observing CFRP in action offers a first-hand experience into how its strength and flexibility drastically changes the architecture of aircrafts.

Automobiles / Bicycles

CFRP is primarily used in racing vehicles and parts (F1 and GT) in the automobile and motorbike industry. In a competitive word where 0.01 second can mean the difference between winning or losing, weight reduction is a key dividing factor.

For automobiles on public roads, CFRP parts are widely used as structural parts for supercars such as Lamborghini and Lexus LFA. However, for mass-market cars, CFRP parts are generally only used as optional parts (hood, roof, and rear spoilers, etc.). The reality is that CFRP still faces many challenges in mass-production and production cost efficiency.

Sports and Leisure Goods

When it comes to the leisure and sports, CFRP products are quite common. Tennis rackets, golf shafts, fishing rods, archery, bicycles, canoes, drones, radio-controlled vehicles, baseball bats, and other products that take advantage of CFRP all offer a first-hand experience of CFRP’s unique characteristics in various situations. Recent demand increases in mountain climbing, hiking and camping industries has further diversified and expanded the amount of weight reducing CFRP products on the market.

CFRP Manufacturing Methods

CFRP offers considerable advantages, but what kinds of manufacturing methods are used to produce it? Here, we will introduce the hallmark molding method for CFRP— autoclave molding.

CFRP Molding Methods

A wide range of molding methods for different applications, shapes, production lots, and so on.

Autoclave Molding

RTM (Resin Transfer Molding)　

Va-RTM (Vacuum Assisted Resin Transfer Molding)

Press Molding

Hand Lay-up Molding

Filament Winding Molding

Sheet Winding Molding

Pultrusion

3D Printer

At Uchida, we use the fabrication methods shown in red.

Autoclave Molding Method: The Hallmark Method for High Quality CFRP Product Manufacturing (Dry Carbon)

Autoclave Molding

Put simply, an autoclave is a pressure device.

Pressure

It pressurizes the inside of the chamber and presses the laminated prepreg sheets against the mold to expel any remaining air.

Temperature

In CFRP (carbon fiber reinforced plastics that use a thermosetting resin) molding, heat causes the resin to react and cure (harden). In the case of CFRTP (carbon fiber reinforced plastics that use a thermoplastic resin) molding, the resin will soften with heat and solidify when cooled. *Similar to chocolate.

Vacuuming

During molding, bagged products are generally vacuumed and air is expelled. The history of the molding process is recorded on paper, or with a digital recording device, and submitted to the client for traceability or stored in accordance with our company’s regulations.

Autoclave

Autoclave internal thermal heating and pressurization processes

Molding

Molding pressures, temperatures, and vacuuming (inert atmosphere) are all programmed to match the product.

Advantages of Autoclave Molding

Advantage #1
Superior Quality and High Reproducibility

Autoclaving uses compressed air to press the material away from the vacuum-backed surface to deliver an evenly applied molding pressure. The prepregs used are quality-controlled stable materials which are not subject to localized pressure during molding. This means that, with the autoclave method, we can produce products which are almost identical (as close as possible) to the design.

Advantage #2

Exceptional Flexibility for Design and Shaping

Offers even greater advantages for larger and more complex profiles.

Choice of any size, provided it fits inside the autoclave chamber.

Advantage #3

Inexpensive Molding Dies

Most products require only concave or convex for molding, thereby reducing mold costs.

Offers wider choices in materials due to the ability to mold with lower pressures (doesn’t require high pressure by press molding).

Disadvantages of Autoclave Molding

Disadvantage #1

Initial equipment installation costs.

Disadvantage #2

Molding lead times are generally takes 4–5 hours.

Summary

This issue covered FRP and carbon fiber reinforced plastic (CFRP) materials. As a cutting-edge material, detailed information is still limited, making it difficult fully comprehend. The general characteristics of FRP are “lightweight, strong, and non-corrosive” properties. CFRP is an impressive and attractive material, but also comes with several disadvantages such as manufacturing complexity and challenges in cost, mass production, and recyclability. We urge you to consider adopting CFRP with full understanding of its advantages and disadvantages.